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Directed self-assembly into low-density colloidal liquid crystal phases

Abstract:

Alignment of anisometric particles into liquid crystals (LCs) often results from an entropic competition between their rotational and translational degrees of freedom at dense packings. Here we show that by selectively functionalizing the heads of colloidal rods with magnetic nanoparticles this tendency can be broken to direct the particles into novel, low-density LC phases. Under an external magnetic field, the magnetic heads line up in columns whereas the nonmagnetic tails point out randoml...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevMaterials.2.015601

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
Christ Church
Role:
Author
Publisher:
American Physical Society Publisher's website
Journal:
Physical Review Materials Journal website
Volume:
2
Issue:
1
Article number:
015601
Publication date:
2018-01-03
Acceptance date:
2017-12-16
DOI:
ISSN:
2475-9953
Source identifiers:
813621
Pubs id:
pubs:813621
UUID:
uuid:dbc6168b-9aa5-436d-8b84-128bb49ca6db
Local pid:
pubs:813621
Deposit date:
2018-01-03

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