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Synthesis and Structure of the New Ternary Nitride SrTiN(2).

Abstract:

A new ternary nitride, SrTiN(2), has been synthesized by the solid-state reaction of Sr(2)N with TiN and characterized by powder X-ray diffraction. SrTiN(2) crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO(2). Titanium is coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layer...

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Publication status:
Published

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Publisher copy:
10.1021/ic971556z

Authors


Gregory, DH More by this author
Barker, MG More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Siddons, DJ More by this author
Journal:
Inorganic chemistry
Volume:
37
Issue:
15
Pages:
3775-3778
Publication date:
1998-07-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:da301352-256f-4455-acfc-d7ab0f6b7009
Source identifiers:
46244
Local pid:
pubs:46244
Language:
English

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