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THE MICROWAVE-SPECTRUM, STRUCTURE, AND HARMONIC FORCE-FIELD OF THE VANDERWAALS TRIMER AR2-OCS

Abstract:

The microwave rotational spectra of the van der Waals trimers Ar 2-OCS, Ar2-OC34S, and Ar2- 18OCS have been observed between 7.0 and 18.0 GHz using pulsed molecular beam microwave Fourier transform (MWFT) spectroscopy. Sixty-five transitions, both a and c type, have been assigned for Ar2-OCS, as well as 37 transitions and 19 transitions for Ar2-OC34S and Ar2-18OCS, respectively. The rotational constants and quartic centrifugal distortion constants have been determined. The trimer has been fou...

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Publication status:
Published

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Publisher copy:
10.1063/1.464155

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
98
Issue:
4
Pages:
2735-2741
Publication date:
1993-02-15
DOI:
ISSN:
0021-9606
URN:
uuid:da1e10eb-1d5b-423e-897d-24452873039b
Source identifiers:
44140
Local pid:
pubs:44140

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