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Experimental and theoretical study of the surface-controlled dissolution of cylindrical particles. Application to solubilization of potassium hydrogen carbonate in hot dimethylformamide.

Abstract:

In this paper we present a mathematical model for the surface-controlled dissolution of cylindrical solid particles. This is employed to interpret experimental data published previously for the dissolution of potassium bicarbonate in dimethylformamide at elevated temperatures. Significant kinetic differences in assuming cylindrical rather than spherical shapes are reported with the former representing a closer approximation to the true shape of the particles as revealed by scanning electron m...

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Publication status:
Published

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Publisher copy:
10.1021/jp058197a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The journal of physical chemistry. B
Volume:
109
Issue:
44
Pages:
20786-20793
Publication date:
2005-11-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:d8e11a6c-57d6-490d-acb7-c1a410d0a6aa
Source identifiers:
33555
Local pid:
pubs:33555

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