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The Stripping Voltammetry of Hemispherical Deposits Under Electrochemically Irreversible Conditions: A Comparison of the Stripping Voltammetry of Bismuth on Boron-Doped Diamond and Au(111) Electrodes

Abstract:

A study of the stripping voltammetry of hemispherical deposits under electrochemically irreversible conditions is presented. Experiments show a difference in the stripping voltammetry of bismuth from a single crystal Au(111) electrode where the bismuth covers the surface in relatively flat film and a boron-doped diamond (BDD) electrode where the hemispherical deposits are seen on the surface. It is shown using mathematical modeling and numerical simulation that this difference cannot be accou...

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Publication status:
Published

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Publisher copy:
10.1021/jp809355n

Authors


Jones, SEW More by this author
Toghill, KE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
113
Issue:
7
Pages:
2846-2854
Publication date:
2009-02-19
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:d8cf95eb-f806-4648-afef-d017556299df
Source identifiers:
41039
Local pid:
pubs:41039
Language:
English

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