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Reactions of titanium imides and hydrazides with boranes

Abstract:

We report the first reactions of titanium imido, alkylidene hydrazido and dimethylhydrazido compounds with the boranes H2BTex, 9-BBN, HBArF 2 and HBPin (Tex = tert-hexyl; ArF = C6F5). Reactions of Cp*Ti{MeC(Ni Pr)2}(NTol) with H2BTex, 9-BBN or HBArF 2 resulted in the hydridebridged adducts Cp*Ti{MeC(Ni Pr2)2}{N(Tol)HBRR′} without B–H bond cleavage. Cp*Ti{MeC(Ni Pr)2}(NNCPh2) (4) reacted with HBArF 2 via a sequence of steps involving adducts at the - and then nitrogen of the NNCPh2 ligand,...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/acs.organomet.7b00477

Authors


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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Oxford, MPLS, Chemistry
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Department:
St Edmund Hall
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Funding agency for:
Mellino, S
University of Oxford SCG Innovation Fund More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
36
Issue:
17
Pages:
3329–3342
Publication date:
2017-08-22
Acceptance date:
2017-08-07
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Pubs id:
pubs:710897
URN:
uri:d8b6a6f0-3d29-4623-8943-c59ab8699ec6
UUID:
uuid:d8b6a6f0-3d29-4623-8943-c59ab8699ec6
Local pid:
pubs:710897

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