Journal article icon

Journal article

The crystal structure and methyl group dynamics in the room-temperature and low-temperature phases of lithium acetate dihydrate

Abstract:

Neutron powder diffraction is used to determine the crystal structure of LiCD3COO · 2D2O at 293 and 1.5 K. Lithium acetate dihydrate crystallizes in the Cmmm space group in the room-temperature phase with a = 6.82082(9) Å, b = 10.88842(12) Å, c = 6.59911(7) Å, and Z = 4. The CH3 groups are dynamically disordered, and there are short H bonds between the water molecules and the acetate oxygen atoms. There is a phase transition to a low-temperature modification which has the space group Pman wit...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1006/jssc.1996.0327

Authors


Kearley, GJ More by this author
Nicolai, B More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Fillaux, F More by this author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
126
Issue:
2
Pages:
184-188
Publication date:
1996-11-01
DOI:
ISSN:
0022-4596
URN:
uuid:d80f0c4c-afde-4fbb-abfc-891f753faa21
Source identifiers:
66396
Local pid:
pubs:66396

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP