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Bis-anthracene fused porphyrins: synthesis, crystal structure, and near-IR absorption.

Abstract:
Synthesis of fused bis-anthracene porphyrin monomers and dimers has been achieved by oxidative ring closure using FeCl(3) and Sc(OTf)(3)/DDQ, respectively. The fused compounds display red-shifted absorption spectra with maxima in the near-IR at 973 and 1495 nm, respectively, and small electrochemical HOMO-LUMO gaps. The crystal structure of the fully fused bis-anthracene porphyrin shows that it has a regular planar pi-system.
Publication status:
Published

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Publisher copy:
10.1021/ol100619p

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
Organic letters
Volume:
12
Issue:
9
Pages:
2124-2127
Publication date:
2010-05-05
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
URN:
uuid:d7eafb8c-d6c4-4ef4-ae0a-2c4bf209c33b
Source identifiers:
52624
Local pid:
pubs:52624

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