- Abstract:
-
In this study, the electrocatalytic (EC′-type) carbon-carbon bond cleavage of cis-1,2-cyclopentanediol by Pb(IV) benzoate generated in situ is shown to be possible under extremely fast mass transport conditions. Based on the comparison of data obtained experimentally and by the numerical simulation of sonoelectrochemical limiting currents with commercially available software (Digisim 2.0), excellent agreement with the theoretical model of a planar diffusion layer can be achieved and allows th...
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- Journal:
- ELECTROANALYSIS
- Volume:
- 10
- Issue:
- 17
- Pages:
- 1188-1192
- Publication date:
- 1998-12-05
- DOI:
- EISSN:
-
1521-4109
- ISSN:
-
1040-0397
- URN:
-
uuid:d75d3c93-8e12-4473-98f1-23624eb6daad
- Source identifiers:
-
36868
- Local pid:
- pubs:36868
- Language:
- English
- Keywords:
- Copyright date:
- 1998
Journal article
Sonoelectrochemically enhanced electrocatalytic processes: The Pb(IV) catalyzed cleavage of 1,2-cis-cyclopentanediol at graphite and glassy carbon electrodes
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