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Synthesis and characterisation of the aminocarbene complexes [(eta(5)-C5H5)Fe(CO)(PPh3){=C(NHR2)(CH2R1)}]+BF4- [R-1 = H, Me or Pr; R-2 = H, Me, Et, CHMe2, CH2Ph, CH(Me)Ph, CH2CH=CH2 or CH2CH2OH]

Abstract:
A number of secondary aminocarbenes of the type (RS)-[(η5-C5H5)Fe(CO)(PPh 3){=C(CH2R1)(NHR2)}] +BF4- were synthesised in very good yield [66-99%, R1 = H, Me or Pr; R2 = H, Me, Et, CHMe2, CH2Ph, CH(Me)Ph, CH2CH=CH2 or CH2CH2OH]. The absolute configuration of one of the carbenes was established by a single-crystal X-ray diffraction experiment. The chemistry of the carbene complexes was investigated.
Publication status:
Published

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Publisher copy:
10.1039/a800927i

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
10
Pages:
1587-1594
Publication date:
1998-05-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:d7479234-04b8-43cf-853b-03d1bed995dd
Source identifiers:
110635
Local pid:
pubs:110635
Language:
English

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