Journal article
Asymmetric Marcus-Hush model of electron transfer kinetics: Application to the voltammetry of surface-bound redox systems
- Abstract:
-
The asymmetric Marcus-Hush model (MH) is applied to the study of the voltammetric response of electroactive monolayers. While the well-documented symmetric MH model has been successful in modelling many aspects of surface-bound redox systems, it cannot account for the asymmetry evident in the Tafel plots for many experimental systems. The asymmetric model has previously been used to explain deviations from the symmetric MH model observed for solution-phase redox systems [E. Laborda, M.C. Hens...
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- Publication status:
- Published
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- Publisher copy:
- 10.1016/j.jelechem.2012.04.006
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Bibliographic Details
- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 674
- Pages:
- 90-96
- Publication date:
- 2012-06-01
- DOI:
- ISSN:
-
1572-6657
- Source identifiers:
-
334499
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:334499
- UUID:
-
uuid:d73d8bf3-aade-4f6f-874e-066388b75fcb
- Local pid:
- pubs:334499
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2012
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