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Asymmetric Marcus-Hush model of electron transfer kinetics: Application to the voltammetry of surface-bound redox systems

Abstract:

The asymmetric Marcus-Hush model (MH) is applied to the study of the voltammetric response of electroactive monolayers. While the well-documented symmetric MH model has been successful in modelling many aspects of surface-bound redox systems, it cannot account for the asymmetry evident in the Tafel plots for many experimental systems. The asymmetric model has previously been used to explain deviations from the symmetric MH model observed for solution-phase redox systems [E. Laborda, M.C. Hens...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
674
Pages:
90-96
Publication date:
2012-06-01
DOI:
ISSN:
1572-6657
URN:
uuid:d73d8bf3-aade-4f6f-874e-066388b75fcb
Source identifiers:
334499
Local pid:
pubs:334499

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