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Asymmetric Marcus-Hush model of electron transfer kinetics: Application to the voltammetry of surface-bound redox systems

Abstract:

The asymmetric Marcus-Hush model (MH) is applied to the study of the voltammetric response of electroactive monolayers. While the well-documented symmetric MH model has been successful in modelling many aspects of surface-bound redox systems, it cannot account for the asymmetry evident in the Tafel plots for many experimental systems. The asymmetric model has previously been used to explain deviations from the symmetric MH model observed for solution-phase redox systems [E. Laborda, M.C. Hens...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
674
Pages:
90-96
Publication date:
2012-06-01
DOI:
ISSN:
1572-6657
Source identifiers:
334499
Language:
English
Keywords:
Pubs id:
pubs:334499
UUID:
uuid:d73d8bf3-aade-4f6f-874e-066388b75fcb
Local pid:
pubs:334499
Deposit date:
2012-12-19

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