- Abstract:
-
The asymmetric Marcus-Hush model (MH) is applied to the study of the voltammetric response of electroactive monolayers. While the well-documented symmetric MH model has been successful in modelling many aspects of surface-bound redox systems, it cannot account for the asymmetry evident in the Tafel plots for many experimental systems. The asymmetric model has previously been used to explain deviations from the symmetric MH model observed for solution-phase redox systems [E. Laborda, M.C. Hens...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2012.04.006
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 674
- Pages:
- 90-96
- Publication date:
- 2012-06-01
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:d73d8bf3-aade-4f6f-874e-066388b75fcb
- Source identifiers:
-
334499
- Local pid:
- pubs:334499
- Language:
- English
- Keywords:
- Copyright date:
- 2012
Journal article
Asymmetric Marcus-Hush model of electron transfer kinetics: Application to the voltammetry of surface-bound redox systems
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