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(C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type

Abstract:

The title compound, bis(propane-1,2-diaminium) tetraaquadi-μ 2-sulfato-disulfatotetraoxodiuranate(VI) dihydrate, (C 3H12N2)2[U2O 4(SO4)4(H2O) 4]·2H2O, contains discrete centrosymmetric anionic {[UO2(H2O)2(SO4)2] 2}4- dimers with C3H12N 22+ cations balancing the charge. The dimers form hydrogen-bonded layers. The cations and occluded water molecules participate in an extensive hydrogen-bonding network. Each UVI centre is seven-coordinate with a pentagonal-bipyramidal geometry. Both pendent and...

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Publication status:
Published

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Publisher copy:
10.1107/S1600536805009682

Authors


Norquist, AJ More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume:
61
Issue:
5
Pages:
M881-M884
Publication date:
2005-05-05
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:d6f662b5-d5ad-4118-9a4f-9c3c97b83f30
Source identifiers:
51164
Local pid:
pubs:51164
Language:
English

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