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Catalytic hydrotrifluoromethylation of unactivated alkenes.

Abstract:
A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF(3) source and MeOH as the reductant is disclosed. This effective transformation operates at room temperature in the presence of 5 mol % Ru(bpy)(3)Cl(2); the process is characterized by its operational simplicity and functional group tolerance.
Publication status:
Published

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Publisher copy:
10.1021/ja401022x

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Journal:
Journal of the American Chemical Society
Volume:
135
Issue:
7
Pages:
2505-2508
Publication date:
2013-02-07
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Source identifiers:
384117
Language:
English
Keywords:
Pubs id:
pubs:384117
UUID:
uuid:d6e83b08-714b-4906-8825-a83b000825ae
Local pid:
pubs:384117
Deposit date:
2013-11-16

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