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Reaction of thiophenol with glucal epoxides: X-ray structure of 3,4,6-tri-O-tert-butyldimethylsilyl-1-S-phenyl-1-thio- alpha-D-glucopyranoside

Abstract:
The reaction of the tert-butyldimethylsilyl protected glucal epoxide 1 with thiophenol under a variety of conditions gives three distinct adducts, including the α-phenylthioglycoside 2a, which exists both in solution and in the solid state in 1C4 conformation in which the C-2, C-3, C-4 and C-5 substituents are all axial.
Publication status:
Published

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Publisher copy:
10.1039/a704534d

Authors


Walford, C More by this author
Jackson, RFW More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
CHEMICAL COMMUNICATIONS
Issue:
19
Pages:
1855-1856
Publication date:
1997-10-07
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:d68e199e-cdfb-4878-890c-144977ffe669
Source identifiers:
115943
Local pid:
pubs:115943
Language:
English

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