Journal article

Transition metal imide organic imine metathesis reactions: unexpected observations

Abstract:: Mixtures of [Ti(NBut)Cl2(py)3] 1 and PhC(NAr)H (Ar = C6H3Me2-2,6 or C6H4Me-4) gave quantitative conversion to [Ti(NAr)Cl2(py)3] and PhC(NBut)H, the products of Ti=N-But/C=NAr transition metal imide/organic imine metathesis; examination of the kinetics for Ar = C6H4Me-4 showed that the rate limiting step for this process is zero order in [1], demonstrating that these reactions do not involve metal imide particiption in the rate limiting step.

Publication status:: Published

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APA Style

McInnes, J., & Mountford, P. (1998). Transition metal imide organic imine metathesis reactions: unexpected observations. CHEMICAL COMMUNICATIONS, 16, 1669–1670.

MLA Style

McInnes, J., and P. Mountford. “Transition Metal Imide Organic Imine Metathesis Reactions: Unexpected Observations.” CHEMICAL COMMUNICATIONS, no. 16, 1998, pp. 1669–70.

Chicago Style

McInnes, J, and P Mountford. 1998. “Transition Metal Imide Organic Imine Metathesis Reactions: Unexpected Observations.” CHEMICAL COMMUNICATIONS, no. 16: 1669–70.
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Publisher copy:: 10.1039/a803719a

Authors

+ McInnes, J More by this author

Role:: Author

+ Mountford, P More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: CHEMICAL COMMUNICATIONS More from this journal
Issue:: 16
Pages:: 1669-1670
Publication date:: 1998-08-21
DOI:: 10.1039/a803719a
EISSN:: 1364-548X
ISSN:: 1359-7345

Pubs id:: pubs:51147
UUID:: uuid:d67d1ec2-79f9-45ed-9f32-167db45c0871
Local pid:: pubs:51147
Source identifiers:: 51147
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1998

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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