- Abstract:
-
Understanding the oxidation of the purines adenine and guanine is primary to improving electrochemical methods of DNA detection and analysis. Adenine in the solution phase is reported to undergo a complex electrochemical oxidation mechanism that is overall a -6H+, -6e- process, involving irreversible chemical steps. The observed voltammetry associated with the oxidation of adenine is strongly dependent upon the electrode used; this is a reflection of both the kinetics of oxidation and strengt...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/jp1046672
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume:
- 114
- Issue:
- 33
- Pages:
- 14213-14219
- Publication date:
- 2010-08-26
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
- URN:
-
uuid:d62bd7b9-0dbd-4c5e-b6a8-8c3ad83bfb3a
- Source identifiers:
-
71210
- Local pid:
- pubs:71210
- Language:
- English
- Copyright date:
- 2010
Journal article
Electrochemical Oxidation of Adenine: A Mixed Adsorption and Diffusion Response on an Edge-Plane Pyrolytic Graphite Electrode
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