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Electrochemical Oxidation of Adenine: A Mixed Adsorption and Diffusion Response on an Edge-Plane Pyrolytic Graphite Electrode

Abstract:

Understanding the oxidation of the purines adenine and guanine is primary to improving electrochemical methods of DNA detection and analysis. Adenine in the solution phase is reported to undergo a complex electrochemical oxidation mechanism that is overall a -6H+, -6e- process, involving irreversible chemical steps. The observed voltammetry associated with the oxidation of adenine is strongly dependent upon the electrode used; this is a reflection of both the kinetics of oxidation and strengt...

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Publication status:
Published

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Publisher copy:
10.1021/jp1046672

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
114
Issue:
33
Pages:
14213-14219
Publication date:
2010-08-26
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:d62bd7b9-0dbd-4c5e-b6a8-8c3ad83bfb3a
Source identifiers:
71210
Local pid:
pubs:71210
Language:
English

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