Journal article
Novel voltammetric responses of a 1,1 '-ferrocene bis(methylene aza-18-crown-6) receptor to group 1 and 2 metal cations in acetonitrile
- Abstract:
-
A 1,1′-ferrocene bis(methylene aza-18-crown-6) ligand (L) and its inclusion complexes with Na+, K+, Ba2+ and Mg2+ are studied in acetonitrile by cyclic and square wave voltammetry. The ligand-metal complex stoichiometry is found to vary from 1:1 to 1:2 with increasing concentration of the metal cation. There is also a binding selectivity for dications over monocations. Simultaneous addition of Mg2+ and Ba2+ gives rise to a novel voltammetric feature which is rationalised by the formation of t...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 444
- Issue:
- 2
- Pages:
- 209-217
- Publication date:
- 1998-03-10
- DOI:
- ISSN:
-
0022-0728
- Source identifiers:
-
36508
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:36508
- UUID:
-
uuid:d5a1adde-adc9-41ad-9d6c-083551140587
- Local pid:
- pubs:36508
- Deposit date:
- 2012-12-19
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- Copyright date:
- 1998
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