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Novel voltammetric responses of a 1,1 '-ferrocene bis(methylene aza-18-crown-6) receptor to group 1 and 2 metal cations in acetonitrile

Abstract:

A 1,1′-ferrocene bis(methylene aza-18-crown-6) ligand (L) and its inclusion complexes with Na+, K+, Ba2+ and Mg2+ are studied in acetonitrile by cyclic and square wave voltammetry. The ligand-metal complex stoichiometry is found to vary from 1:1 to 1:2 with increasing concentration of the metal cation. There is also a binding selectivity for dications over monocations. Simultaneous addition of Mg2+ and Ba2+ gives rise to a novel voltammetric feature which is rationalised by the formation of t...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
444
Issue:
2
Pages:
209-217
Publication date:
1998-03-10
DOI:
ISSN:
0022-0728
Source identifiers:
36508
Language:
English
Keywords:
Pubs id:
pubs:36508
UUID:
uuid:d5a1adde-adc9-41ad-9d6c-083551140587
Local pid:
pubs:36508
Deposit date:
2012-12-19

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