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THE STRUCTURE OF CO(ETA-C5H5)(2)(+) AND NME(4)(+) INTERCALATES OF MNPS3 - AN X-RAY, NEUTRON-DIFFRACTION, AND SOLID-STATE NMR-STUDY

Abstract:

This paper reports a series of structural studies on the intercalation compounds of MnPS3, with the aim of trying to understand the source of the magnetic and NLO properties they exhibit. Both neutron and X-ray powder experiments and single crystal studies have been performed on Mn1-xPS3{G}2x(H2O)y for G = Co(η-C5H5)2+ [x = 0.34, y = 0.3] and N(CH3)4+ [x = 0.32, y = 0.9]. These investigations have suggested that the individual host layers of these intercalates contain an ordered arrangement o...

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Publication status:
Published

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Publisher copy:
10.1021/ja00121a017
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY More from this journal
Volume:
117
Issue:
16
Pages:
4595-4606
Publication date:
1995-04-26
DOI:
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:51486
UUID:
uuid:d580f52c-4c35-4822-8af9-3c8ba23b1c80
Local pid:
pubs:51486
Source identifiers:
51486
Deposit date:
2012-12-19

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