- Abstract:
-
Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F](2+) and [Yb⋅DTMA⋅OH2 ](3+) are in slow exchange on the relevant NMR timescale (<2000 s(-1) ), and profound differences are observed in their respective NMR and EPR spectra of these species. The observed differences can be explained by drastic modification of the ligand field states due to the fluoride binding. This changes the magnetic anisotrop...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 1.3mb)
-
- Publisher copy:
- 10.1002/anie.201503421
-
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- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie (International ed. in English) Journal website
- Volume:
- 54
- Issue:
- 37
- Pages:
- 10783-10786
- Publication date:
- 2015-09-05
- DOI:
- EISSN:
-
1521-3773
- ISSN:
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1433-7851
- URN:
-
uuid:d51e9b7b-77db-4337-9899-12315e976608
- Source identifiers:
-
535602
- Local pid:
- pubs:535602
- Language:
- English
- Keywords:
- Copyright holder:
- Faulkner et al
- Copyright date:
- 2015
- Notes:
- © 2015 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Journal article
Spectroscopic and crystal field consequences of fluoride binding by [Yb⋅DTMA](3+) in aqueous solution.
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The University of Manchester
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