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Spectroscopic and crystal field consequences of fluoride binding by [Yb⋅DTMA](3+) in aqueous solution.

Abstract:

Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F](2+) and [Yb⋅DTMA⋅OH2 ](3+) are in slow exchange on the relevant NMR timescale (<2000 s(-1) ), and profound differences are observed in their respective NMR and EPR spectra of these species. The observed differences can be explained by drastic modification of the ligand field states due to the fluoride binding. This changes the magnetic anisotrop...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1002/anie.201503421

Authors


Blackburn, OA More by this author
Chilton, NF More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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The University of Manchester More from this funder
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie (International ed. in English) Journal website
Volume:
54
Issue:
37
Pages:
10783-10786
Publication date:
2015-09-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:d51e9b7b-77db-4337-9899-12315e976608
Source identifiers:
535602
Local pid:
pubs:535602

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