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Neutron diffraction study of Ba6Mn4MO15 (M = Cu, Zn): Long-range magnetic order in pseudo-1D materials

Abstract:

The room-temperature crystal structures of Ba6Mn4MO15 (M = Zn, Cu) have been refined using X-ray and neutron powder diffraction data simultaneously. Ba6Mn4ZnO15 is isostructural with Ba6Ni5O15 and contains transition metals in chains of oxide polyhedra (trigonal prisms and octahedra); neighboring chains are separated from each other by the Ba atoms. Zn and Mn occupy the trigonal prismatic site in equal concentrations, with the remaining Zn and Mn partially ordered over the two crystallographi...

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Publication status:
Published

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Publisher copy:
10.1021/ja984313u

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume:
121
Issue:
16
Pages:
3958-3967
Publication date:
1999-04-28
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:d5004507-8bb8-4b4c-bac6-d9fc8468b48c
Source identifiers:
37010
Local pid:
pubs:37010
Language:
English

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