- Abstract:
-
The room-temperature crystal structures of Ba6Mn4MO15 (M = Zn, Cu) have been refined using X-ray and neutron powder diffraction data simultaneously. Ba6Mn4ZnO15 is isostructural with Ba6Ni5O15 and contains transition metals in chains of oxide polyhedra (trigonal prisms and octahedra); neighboring chains are separated from each other by the Ba atoms. Zn and Mn occupy the trigonal prismatic site in equal concentrations, with the remaining Zn and Mn partially ordered over the two crystallographi...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ja984313u
-
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- Journal:
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume:
- 121
- Issue:
- 16
- Pages:
- 3958-3967
- Publication date:
- 1999-04-28
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:d5004507-8bb8-4b4c-bac6-d9fc8468b48c
- Source identifiers:
-
37010
- Local pid:
- pubs:37010
- Language:
- English
- Copyright date:
- 1999
Journal article
Neutron diffraction study of Ba6Mn4MO15 (M = Cu, Zn): Long-range magnetic order in pseudo-1D materials
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