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Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units

Abstract:

The reactivity of two paramagnetic nickel(I) compounds, CpNi(NHC) (where Cp = cyclopentadienyl; NHC = 1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylidene (IMes) or 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr)), towards [Na(dioxane)x][PnCO] (Pn = P, As) is described. These reactions afford symmetric bimetallic compounds (µ2:η2,η2-Pn2){Ni(NHC)(CO)}2. Several novel intermediates en route to such species are identified and characterised, including a compound containing the PCO- anion in ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201710582

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
ORCID:
0000-0002-7831-1410
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall
Role:
Author
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Name:
Bayer Foundation
Grant:
Otto Bayer fellowship for G.H
More from this funder
Name:
Engineering and Physical Sciences Research Council
Grant:
EP/M027732/1
Publisher:
Wiley
Journal:
Angewandte Chemie International Edition More from this journal
Volume:
57
Issue:
2
Pages:
431–436
Publication date:
2017-12-06
Acceptance date:
2017-11-11
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
29152826
Language:
English
Keywords:
Pubs id:
pubs:806775
UUID:
uuid:d4eeea03-f251-46bc-ae4f-ce9c4a991313
Local pid:
pubs:806775
Source identifiers:
806775
Deposit date:
2017-12-01

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