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Highly electron rich β-diketiminato systems: Synthesis and coordination chemistry of amino functionalized 'N-nacnac' ligands

Abstract:

The synthesis of a class of electron-rich amino-functionalized β-diketiminato (N-nacnac) ligands is reported, with two synthetic methodologies having been developed for systems bearing backbone NMe2 or NEt2 groups and a range of N-bound aryl substituents. In contrast to their (Nacnac)H counterparts, the structures of the protio-ligands feature the bis(imine) tautomer and a backbone CH2 group. Direct metallation with lithium, magnesium or aluminium alkyls allows access to the respective metal ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201700757

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Grant:
Marie Curie program (ELK, grant number PIEF-GA-2013-626441)
Australian Research Council More from this funder
Publisher:
Wiley-VCH Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
23
Issue:
24
Pages:
5830–5841
Publication date:
2017-03-02
Acceptance date:
2017-03-02
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Source identifiers:
684216
Pubs id:
pubs:684216
UUID:
uuid:d4e6f35c-ab0d-4725-9d1d-67b8e56fb1ed
Local pid:
pubs:684216
Deposit date:
2017-03-08

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