Journal article
Highly electron rich β-diketiminato systems: Synthesis and coordination chemistry of amino functionalized 'N-nacnac' ligands
- Abstract:
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The synthesis of a class of electron-rich amino-functionalized β-diketiminato (N-nacnac) ligands is reported, with two synthetic methodologies having been developed for systems bearing backbone NMe2 or NEt2 groups and a range of N-bound aryl substituents. In contrast to their (Nacnac)H counterparts, the structures of the protio-ligands feature the bis(imine) tautomer and a backbone CH2 group. Direct metallation with lithium, magnesium or aluminium alkyls allows access to the respective metal ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 12.0MB)
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- Publisher copy:
- 10.1002/chem.201700757
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Authors
Funding
+ European Union
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Grant:
Marie Curie program (ELK, grant number PIEF-GA-2013-626441)
Australian Research Council
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Bibliographic Details
- Publisher:
- Wiley-VCH Publisher's website
- Journal:
- Chemistry - A European Journal Journal website
- Volume:
- 23
- Issue:
- 24
- Pages:
- 5830–5841
- Publication date:
- 2017-03-02
- Acceptance date:
- 2017-03-02
- DOI:
- EISSN:
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1521-3765
- ISSN:
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0947-6539
- Source identifiers:
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684216
Item Description
- Pubs id:
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pubs:684216
- UUID:
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uuid:d4e6f35c-ab0d-4725-9d1d-67b8e56fb1ed
- Local pid:
- pubs:684216
- Deposit date:
- 2017-03-08
Terms of use
- Copyright holder:
- Wiley-VCH
- Copyright date:
- 2017
- Notes:
- © 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley at: 10.1002/chem.201700757
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