Journal article icon

Journal article

Highly electron rich β-diketiminato systems: Synthesis and coordination chemistry of amino functionalized 'N-nacnac' ligands

Abstract:

The synthesis of a class of electron-rich amino-functionalized β-diketiminato (N-nacnac) ligands is reported, with two synthetic methodologies having been developed for systems bearing backbone NMe2 or NEt2 groups and a range of N-bound aryl substituents. In contrast to their (Nacnac)H counterparts, the structures of the protio-ligands feature the bis(imine) tautomer and a backbone CH2 group. Direct metallation with lithium, magnesium or aluminium alkyls allows access to the respective metal ...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

Actions


Access Document


Files:
Publisher copy:
10.1002/chem.201700757

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Expand authors...
More from this funder
Funding agency for:
Do, DCH
More from this funder
Grant:
Marie Curie program (ELK, grant number PIEF-GA-2013-626441)
Australian Research Council More from this funder
Publisher:
Wiley-VCH Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
23
Issue:
24
Pages:
5830–5841
Publication date:
2017-03-02
Acceptance date:
2017-03-02
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:684216
URN:
uri:d4e6f35c-ab0d-4725-9d1d-67b8e56fb1ed
UUID:
uuid:d4e6f35c-ab0d-4725-9d1d-67b8e56fb1ed
Local pid:
pubs:684216
Paper number:
24

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP