- Abstract:
-
A reversible electron transfer is studied at a microdisk electrode which is partially blocked by an inert particle at the disk center. The inert particle is either a cylinder of a sphere. The size of a cylinder located at the center of the microdisk electrode is determined with the help of a simple electrochemical procedure. Cyclic voltammograms for the reduction of a reversible redox system are recorded as a function of scan rate and compared to simulations. Excellent agreement between theor...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2007.08.021
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 611
- Issue:
- 1-2
- Pages:
- 201-207
- Publication date:
- 2007-12-15
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:d4af2e66-ac9f-42a6-a355-a5cfda860f6b
- Source identifiers:
-
40557
- Local pid:
- pubs:40557
- Language:
- English
- Keywords:
- Copyright date:
- 2007
Journal article
Voltammetric sizing and shaping of a cylinder
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