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Voltammetric sizing and shaping of a cylinder

Abstract:

A reversible electron transfer is studied at a microdisk electrode which is partially blocked by an inert particle at the disk center. The inert particle is either a cylinder of a sphere. The size of a cylinder located at the center of the microdisk electrode is determined with the help of a simple electrochemical procedure. Cyclic voltammograms for the reduction of a reversible redox system are recorded as a function of scan rate and compared to simulations. Excellent agreement between theor...

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Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
611
Issue:
1-2
Pages:
201-207
Publication date:
2007-12-15
DOI:
ISSN:
1572-6657
Language:
English
Keywords:
Pubs id:
pubs:40557
UUID:
uuid:d4af2e66-ac9f-42a6-a355-a5cfda860f6b
Local pid:
pubs:40557
Source identifiers:
40557
Deposit date:
2012-12-19

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