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Intercalation chemistry of the novel layered double hydroxides [MAl4(OH)(12)](NO3)(2)center dot gamma H2O (M = Zn, Cu, Ni and Co). 1: New organic intercalates and reaction mechanisms

Abstract:

The intercalation chemistry of a recently synthesized family of layered double hydroxides, [MAl4(OH)12](NO3) 2·yH2O (M = Zn, Cu, Ni, Co), has been explored. A range of dicarboxylates, mono- and disulfonates have been intercalated successfully, and the resulting materials fully characterised. The interlayer spacing of the dicarboxylates is found not to vary linearly with the length of the carboxylate chain, but instead the acid species are arranged so that the ends of the dicarboxylate chains ...

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Publication status:
Published

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Publisher copy:
10.1039/b514874j

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF MATERIALS CHEMISTRY More from this journal
Volume:
16
Issue:
13
Pages:
1222-1230
Publication date:
2006-01-01
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
Language:
English
Pubs id:
pubs:51301
UUID:
uuid:d4ae9ae9-3ad1-4fe7-bbee-c9a7f330342b
Local pid:
pubs:51301
Source identifiers:
51301
Deposit date:
2012-12-19

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