Journal article icon

Journal article

Intramolecular hydrogen bonding in chiral alcohols: The microwave spectrum of the chloropropanols

Abstract:

The microwave Fourier transform spectrum of a mixture of 1-chloropropan-2-ol and 2-chloropropan-1-ol has been recorded in the range 5-18 GHz. The spectrum is extremely dense, as a result of both the large number of species present in the supersonic expansion, and the splitting of rotational transitions due to quadrupole coupling. Two conformational isomers of each molecule have been identified, and both the 35Cl and 37Cl isotopomers have been observed for both conformations of 1-chloropropan-...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1016/j.jms.2005.11.010

Authors


Goldstein, T More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF MOLECULAR SPECTROSCOPY
Volume:
236
Issue:
1
Pages:
1-10
Publication date:
2006-03-05
DOI:
EISSN:
1096-083X
ISSN:
0022-2852
URN:
uuid:d48e4de0-d1e0-4c71-aaf1-73c2f7d577de
Source identifiers:
39846
Local pid:
pubs:39846

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP