- Abstract:
-
The effect of bismuth adsorption on the entropy of formation of the double layer on Pt(111) electrodes has been studied with the laser-induced temperature jump method. The coulostatic response to the temperature change induced by pulsed laser illumination allows the estimation of the sign and magnitude of the thermal coefficient of the potential drop at the interphase. This is related to the entropy of formation of the double layer, and the particular potential where this thermal coefficient ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/jp061982i
-
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- Journal:
- The journal of physical chemistry. B
- Volume:
- 110
- Issue:
- 42
- Pages:
- 21092-21100
- Publication date:
- 2006-10-05
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1520-6106
- URN:
-
uuid:d47c0867-8340-4212-9a3a-6011ffe92613
- Source identifiers:
-
40142
- Local pid:
- pubs:40142
- Language:
- English
- Copyright date:
- 2006
Journal article
Effect of deposited bismuth on the potential of maximum entropy of Pt(111) single-crystal electrodes.
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