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Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands

Abstract:

New ligand systems containing two 2,2′-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4′-bipyridinediium, N,N′,N″-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared. A variety of homometallic Copper(I) complexes have been isolated and fast atom bombardment mass spectrometry investigations suggest most of the complexes to be of general formula [Cu2L2][PF6]2. Solution 1H NM...

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Publisher copy:
10.1039/DT9920002667

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Wheeler, JW More by this author
Journal:
Journal of the Chemical Society, Dalton Transactions
Issue:
18
Pages:
2667-2673
Publication date:
1992
DOI:
ISSN:
1472-7773
URN:
uuid:d473893f-c559-43c5-a0ab-763e56e7fc31
Source identifiers:
134284
Local pid:
pubs:134284
Language:
English

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