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The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.

Abstract:

Iridium hydridophosphine complexes of general formula [Ir(PR3)2H2(anion)](PR3= PPh3, PMe2Ph; anion =[1-closo-CB(11)H(6)Cl(6)]-, [1-closo-CB(11)H(6)I(6)]-, [BAr(F)4]-) have been prepared by hydrogenation of cyclooctadiene precursor complexes. Solid-state structures of selected examples of these complexes reveal intimate contacts between the carborane anion and cation, with the anion binding through two lower-hemisphere halogen ligands. In CD2Cl2 solution the very weakly coordinating anions [1-...

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Publication status:
Published

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Publisher copy:
10.1039/b612049k

Authors


Moxham, GL More by this author
Douglas, TM More by this author
Brayshaw, SK More by this author
Kociok-Köhn, G More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
46
Pages:
5492-5505
Publication date:
2006-12-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:d439a2fa-ffa1-4e9d-960c-e7b9cd89358b
Source identifiers:
51696
Local pid:
pubs:51696
Language:
English

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