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The monohydrate and dihydrate of acetic acid: a high-resolution microwave spectroscopic study.

Abstract:

High-resolution microwave spectra of the monohydrate and dihydrate of acetic acid were recorded using a pulsed nozzle Fourier transform microwave spectrometer. The rotational and centrifugal distortion constants of these species were determined, which confirms the structures predicted by ab initio calculations that the H(2)O molecules bind to the carboxylic group to form hydrogen-bonded ring complexes. The dependence of the intensity of the rotational transitions on the power of the microwave...

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Publication status:
Published

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Publisher copy:
10.1039/b814562h

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
11
Issue:
2
Pages:
366-373
Publication date:
2009-01-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:d3f64dca-ed85-4de9-b5b5-e9ca4f0fbb05
Source identifiers:
34525
Local pid:
pubs:34525
Language:
English

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