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The monohydrate and dihydrate of acetic acid: a high-resolution microwave spectroscopic study.

Abstract:

High-resolution microwave spectra of the monohydrate and dihydrate of acetic acid were recorded using a pulsed nozzle Fourier transform microwave spectrometer. The rotational and centrifugal distortion constants of these species were determined, which confirms the structures predicted by ab initio calculations that the H(2)O molecules bind to the carboxylic group to form hydrogen-bonded ring complexes. The dependence of the intensity of the rotational transitions on the power of the microwave...

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Publication status:
Published

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Publisher copy:
10.1039/b814562h

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
11
Issue:
2
Pages:
366-373
Publication date:
2009-01-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
34525
Language:
English
Pubs id:
pubs:34525
UUID:
uuid:d3f64dca-ed85-4de9-b5b5-e9ca4f0fbb05
Local pid:
pubs:34525
Deposit date:
2012-12-19

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