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Total synthesis of the Glc(3)Man N-glycan tetrasaccharide

Abstract:

The total synthesis of the tetrasaccharide Glcα(1→2)Glcα(1→3)Glcα(1→3)ManαOMe, which corresponds to the terminal tetrasaccharide portion of the glucose terminated arm of the N-glycan tetradecasaccharide, was achieved by the use of differentially protected selenoglycosides and thioglycosides as glycosyl donors, all of which possessed non-participating protection of the 2-hydroxyl group. Favourable anomeric stereoselectivity was achieved for the glycosylation reactions by the use of ether as so...

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Publication status:
Published

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Authors


Cumpstey, I More by this author
Fairbanks, AJ More by this author
Butters, TD More by this author
Mackeen, M More by this author
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Journal:
TETRAHEDRON
Volume:
58
Issue:
46
Pages:
9403-9411
Publication date:
2002-11-11
DOI:
ISSN:
0040-4020
URN:
uuid:d3dc11ab-61c4-4995-9a9e-a6241dbf529a
Source identifiers:
100424
Local pid:
pubs:100424

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