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Beta-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten.

Abstract:

Reactions of bis(imido) compounds (RN)(2)Mo(PMe(3))(n) (n = 2, R = (t)Bu; n = 3, R =2,6-dimethylphenyl (Ar') and 2,6-diisopropylphenyl (Ar)) and (RN)(2)W(PMe(3))(3) (R = 2,6-dimethylphenyl and 2,6-diisopropylphenyl) with silanes afford four types of products: the beta-agostic silylamido compounds (RN)(eta(3)-RN-SiR'(2)-H...)MCl(PMe(3))(2) (M = Mo and W), mono(imides) (RN)MCl(2)(PMe(3))(3) (M = Mo and W), silyl hydride bis(imido) derivative (ArN)(2)W(PMe(3))(H)(SiMeCl(2)), and Si-Cl...W bridge...

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Publication status:
Published

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Publisher copy:
10.1021/ic900591e

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
48
Issue:
20
Pages:
9605-9622
Publication date:
2009-10-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:d2daeb5e-89c1-4d17-9d4d-2016b992febb
Source identifiers:
51248
Local pid:
pubs:51248
Language:
English

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