Reactions of bis(imido) compounds (RN)(2)Mo(PMe(3))(n) (n = 2, R = (t)Bu; n = 3, R =2,6-dimethylphenyl (Ar') and 2,6-diisopropylphenyl (Ar)) and (RN)(2)W(PMe(3))(3) (R = 2,6-dimethylphenyl and 2,6-diisopropylphenyl) with silanes afford four types of products: the beta-agostic silylamido compounds (RN)(eta(3)-RN-SiR'(2)-H...)MCl(PMe(3))(2) (M = Mo and W), mono(imides) (RN)MCl(2)(PMe(3))(3) (M = Mo and W), silyl hydride bis(imido) derivative (ArN)(2)W(PMe(3))(H)(SiMeCl(2)), and Si-Cl...W bridge...Expand abstract
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Beta-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten.
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