Journal article icon

Journal article

Sensitised near-infrared luminescence from lanthanide(III) centres using Re(I) and Pt(II) diimine complexes as energy donors in d-f dinuclear complexes based on 2,3-bis(2-pyridyl)pyrazine.

Abstract:

The luminescent transition metal complexes [Re(CO)(3)Cl(bppz)] and [Pt(CC-C(6)H(4)CF(3))(2)(bppz)] [bppz = 2,3-bis(2-pyridyl)pyrazine], in which one of the diimine binding sites of the potentially bridging ligand bppz is vacant, have been used as 'complex ligands' to make heterodinuclear d-f complexes by attachment of a {Ln(dik)(3)} fragment (dik = a 1,3-diketonate) at the vacant site. When Ln = Pr, Nd, Er or Yb the lanthanide centre has low-energy f-f excited states capable of accepting ener...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/b616423d

Authors


Kennedy, F More by this author
Shavaleev, NM More by this author
Koullourou, T More by this author
Jeffery, JC More by this author
Expand authors...
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
15
Pages:
1492-1499
Publication date:
2007-04-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:d2a4e016-40b8-4dc7-8ec8-19642a8021dc
Source identifiers:
40287
Local pid:
pubs:40287
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP