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Dynamic simulation of the moving boundary method for measuring transference numbers

Abstract:

The Nernst-Planck-Poisson (NPP) finite difference method is used to simulate a moving boundary experiment of an aqueous system with HCl and CdCl2 salts, as used to determine the transference number of H + according to the classical method [D.A. MacInnes et al., Chem. Rev. 11 (1932) 171-230]. Theoretical predictions used in inferring transference numbers from moving boundary experiments are confirmed, and the presence of charge separation in the vicinity of the moving boundary is demonstrated....

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Publication status:
Published

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Authors


Dickinson, EJF More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
513
Issue:
1-3
Pages:
136-138
Publication date:
2011-09-06
DOI:
ISSN:
0009-2614
URN:
uuid:d24592e7-a2fc-4dd2-9806-36f6ca731350
Source identifiers:
175508
Local pid:
pubs:175508
Language:
English

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