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Journal article

Structural trends in ten-vertex endohedral clusters, M@E(10) and the synthesis of a new member of the family, [Fe@Sn10]3-.

Abstract:

The synthesis of a new endohedral ten-vertex Zintl ion cluster, [Fe@Sn10](3-), isoelectronic with [Fe@Ge10](3-), is reported. In an attempt to place this new cluster within the context of the known structural chemistry of the M@E10 family (M = transition metal, E = main group element), we have carried out a detailed electronic structure analysis of the different structural types: viz bicapped square antiprismatic ([Ni@Pb10](2-), [Zn@In10](8-)), tetra-capped trigonal prismatic ([Ni@In10](10-))...

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Publication status:
Published

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Publisher copy:
10.1039/c3dt50643f

Authors


Krämer, T More by this author
Duckworth, JC More by this author
Ingram, MD More by this author
McGrady, JE More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
42
Issue:
34
Pages:
12120-12129
Publication date:
2013-09-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:d2415e47-3c5c-4fb3-9db0-bacad58f23d9
Source identifiers:
401832
Local pid:
pubs:401832
Language:
English

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