Journal article
Lattice dynamics and negative thermal expansion in the framework compound ZnNi(CN)4 with two-dimensional and three-dimensional local environments
- Abstract:
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ZnNi(CN)4 is a three-dimensional (3D) framework material consisting of two interpenetrating PtS-type networks in which tetrahedral [ZnN4] units are linked by square-planar [NiC4] units. Both the parent compounds, cubic Zn(CN)2 and layered Ni(CN)2, are known to exhibit 3D and 2D negative thermal expansion (NTE), respectively. Temperature-dependent inelastic neutron scattering measurements were performed on a powdered sample of ZnNi(CN)4 to probe phonon dynamics. The measurements were underpinn...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
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(pdf, 1.7MB)
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- Publisher copy:
- 10.1103/physrevb.99.024309
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Authors
Bibliographic Details
- Publisher:
- American Physical Society Publisher's website
- Journal:
- Physical Review B Journal website
- Volume:
- 99
- Issue:
- 2
- Pages:
- Article: 024309
- Publication date:
- 2019-01-22
- Acceptance date:
- 2019-01-02
- DOI:
- EISSN:
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2469-9969
- ISSN:
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2469-9950
- Pubs id:
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pubs:966340
- URN:
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uri:d117dd33-29ad-4011-b537-477814164edb
- UUID:
-
uuid:d117dd33-29ad-4011-b537-477814164edb
- Local pid:
- pubs:966340
Item Description
- Language:
- English
Terms of use
- Copyright holder:
- American Physical Society
- Copyright date:
- 2019
- Notes:
-
Copyright © 2019 American Physical Society. This is the accepted manuscript version of the article. The final version is available online from American Physical Society at: https://doi.org/10.1103/physrevb.99.024309
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