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Alkyl and aryl dicationic derivatives of cyclic triphosphenium ions.

Abstract:

Direct alkylation of cyclic triphosphenium ions by triflates to give di-ium dications is only possible for small organic substituents on the attacking reagent. The dicationic products are not intrinsically unstable, however, and in many instances they may be synthesised by an alternative route, pioneered by Schmidpeter and co-workers. These species may be readily identified in solution by (31)P NMR spectroscopy. The crystal and molecular structures of five such derivatives have been ascertain...

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Publication status:
Published

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Publisher copy:
10.1039/b716027e

Authors


Journal:
Dalton transactions (Cambridge, England : 2003) More from this journal
Issue:
9
Pages:
1144-1149
Publication date:
2008-03-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Language:
English
Pubs id:
pubs:117134
UUID:
uuid:d0dd0973-630c-4167-9ced-4b4f7e12fbc1
Local pid:
pubs:117134
Source identifiers:
117134
Deposit date:
2012-12-19

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