Journal article icon

Journal article

Anomalous nuclear overhauser effects in carbon-substituted aziridines: Scalar cross-relaxation of the first kind

Abstract:

Anomalous NOESY cross-peaks that cannot be explained by dipolar cross-relaxation or chemical exchange are described for carbon-substituted aziridines. The origin of these is identified as scalar cross-relaxation of the first kind, as demonstrated by a complete theoretical description of this relaxation process and by computational simulation of the NOESY spectra. It is shown that this process relies on the stochastic modulation of J-coupling by conformational transitions, which in the case of...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1002/anie.201410271

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Expand authors...
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie - International Edition Journal website
Volume:
54
Issue:
12
Pages:
3697-3701
Publication date:
2015-03-16
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
510421
Keywords:
Pubs id:
pubs:510421
UUID:
uuid:d0cd1a8f-6d1c-4304-a93f-7211d244ad11
Local pid:
pubs:510421
Deposit date:
2015-07-13

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP