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Structural and magnetic characterization of La2NiRhO6

Abstract:

A polycrystalline sample of the perovskite La2NiRhO6 has been prepared. Neutron diffraction shows the compound to be orthorhombic (space group Pbnm; a=5.5350(4), b=5.5529(4), and c=7.8305(5) Å at 5 K) with a disordered arrangement of Ni and Rh over the six-coordinate B sites. Consideration of the B-O bond lengths and the paramagnetic Curie constant suggests that the Ni and Rh cations are trivalent and low spin. Magnetization and neutron diffraction experiments show that a transition to a spin...

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Publication status:
Published

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Publisher copy:
10.1006/jssc.1999.8324

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
146
Issue:
1
Pages:
163-167
Publication date:
1999-08-05
DOI:
ISSN:
0022-4596
URN:
uuid:d0c2e07c-702d-494c-ac4b-3d2feef81160
Source identifiers:
37030
Local pid:
pubs:37030
Language:
English

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