- Abstract:
-
A polycrystalline sample of the perovskite La2NiRhO6 has been prepared. Neutron diffraction shows the compound to be orthorhombic (space group Pbnm; a=5.5350(4), b=5.5529(4), and c=7.8305(5) Å at 5 K) with a disordered arrangement of Ni and Rh over the six-coordinate B sites. Consideration of the B-O bond lengths and the paramagnetic Curie constant suggests that the Ni and Rh cations are trivalent and low spin. Magnetization and neutron diffraction experiments show that a transition to a spin...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1006/jssc.1999.8324
-
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- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY
- Volume:
- 146
- Issue:
- 1
- Pages:
- 163-167
- Publication date:
- 1999-08-05
- DOI:
- ISSN:
-
0022-4596
- URN:
-
uuid:d0c2e07c-702d-494c-ac4b-3d2feef81160
- Source identifiers:
-
37030
- Local pid:
- pubs:37030
- Language:
- English
- Copyright date:
- 1999
Journal article
Structural and magnetic characterization of La2NiRhO6
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