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Unique layered double hydroxide morphologies using reverse microemulsion synthesis.

Abstract:

We report the first controlled synthesis of a layered double hydroxide (LDH) in a water-in-oil reverse microemulsion system. This synthesis of Mg2Al-LDHs was carried out in the reverse microemulsion of NaDDS (sodium dodecyl sulfate)-water-isooctane with water/surfactant molar ratio = 24. This enables us to obtain nanometer sized LDH platelets typically with a 40-50 nm diameter and 10 nm thickness. Further modification of the reverse microemulsion using triblock copolymers during crystallizati...

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Publication status:
Published

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Publisher copy:
10.1021/ja0549392

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Journal of the American Chemical Society
Volume:
127
Issue:
50
Pages:
17808-17813
Publication date:
2005-12-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:d0bf3890-1c48-4604-946f-3a72a9efb115
Source identifiers:
51309
Local pid:
pubs:51309
Language:
English

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