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ROTATIONAL AND VIBRATIONAL-ROTATIONAL RELAXATION IN COLLISIONS OF CO2(0110) WITH HE ATOMS

Abstract:

Rotational and vibrational-rotational relaxation of CO2(01 10) in collisions with He atoms is studied theoretically. Cross sections and rate coefficients have been calculated using a vibrational close-coupling, rotational infinite-order sudden method, together with an ab initio potential energy surface. Comparisons with previous calculations and experiments on rotational relaxation in He+CO2(0001) are made. The rotational relaxation cross sections are found to be insensitive to the vibrationa...

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Publication status:
Published

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Publisher copy:
10.1063/1.445401

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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
78
Issue:
8
Pages:
4915-4923
Publication date:
1983
DOI:
ISSN:
0021-9606
URN:
uuid:d0be4e15-da00-4ddb-91de-e5a2b6742dba
Source identifiers:
52799
Local pid:
pubs:52799
Language:
English

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