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Half-Sandwich Group 8 Borylene Complexes: Synthetic and Structural Studies and Oxygen Atom Abstraction Chemistry

Abstract:

Cationic terminal borylene complexes, synthesized by halide abstraction, offer a versatile platform on which to gauge the effects on the electronic structure of the metal-ligand bond brought about by variation in the borylene substituent and the metal/ligand framework. While the borylene substituent exerts a strong influence on boron-centered electrophilicity and hence on metal-ligand n character and bond length (e.g., from 1.792(8) Å for [Cp Fe(CO)2(BMes)]-to 2.049(4) Å for [CpFe(CO) 2{ B(NC...

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Publication status:
Published

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Publisher copy:
10.1021/om801215b

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
28
Issue:
10
Pages:
2947-2960
Publication date:
2009-05-25
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:41195
UUID:
uuid:d028b0c3-c642-4bd0-96d8-2dae6297b4ad
Local pid:
pubs:41195
Source identifiers:
41195
Deposit date:
2012-12-19

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