Journal article icon

Journal article

Cyclic alkenylsulfonyl fluorides: palladium‐catalyzed synthesis and functionalization of compact multifunctional reagents

Abstract:

A series of low‐molecular‐weight, compact, and multifunctional cyclic alkenylsulfonyl fluorides were efficiently prepared from the corresponding alkenyl triflates. Palladium‐catalyzed sulfur dioxide insertion using the surrogate reagent DABSO effects sulfinate formation, before trapping with an F electrophile delivers the sulfonyl fluorides. A broad range of functional groups are tolerated, and a correspondingly large collection of derivatization reactions are possible on the products, includ...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1002/ange.201910871

Authors


More by this author
Role:
Author
ORCID:
0000-0003-0226-6251
More by this author
Role:
Author
ORCID:
0000-0002-7365-7332
More by this author
Department:
CHEMISTRY
Sub department:
Organic Chemistry
Role:
Author
ORCID:
0000-0002-0636-6471
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie Journal website
Volume:
131
Issue:
52
Pages:
19035-19039
Publication date:
2019-11-06
Acceptance date:
2019-10-14
DOI:
EISSN:
1521-3757
ISSN:
0044-8249
Language:
English
Keywords:
Pubs id:
1071427
Local pid:
pubs:1071427
Deposit date:
2020-02-05

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP