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New binuclear alkyl and half-sandwich cyclopentadienyl imido titanium complexes containing acetamidinate and benzamidinate supporting ligands

Abstract:

Chloride metathesis reactions of the binuclear titanium N,N′-bis(cyclohexyl)acetamidinato-μ-imido compound [Ti2(μ-NBut)2{MeC(NC6H11)2}2Cl2] (1) and the mononuclear N,N′-bis(trimethylsilyl)benzamidinato-imido analogue [Ti(NBut){PhC(NSiMe3)2}Cl(py)2] (2) are described. Thus, reaction of 1 or 2 with LiC5R5 (R=H or Me) gave the half-sandwich compounds [Ti(NBut){MeC(NC6H11)2}(η-C 5H5)] and [Ti(NBut){PhC(NSiMe3)2}(η-C5Me5)], respectively. These compounds are also accessible from [Ti(NBut)(η-C5R5)Cl...

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Publication status:
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
564
Issue:
1-2
Pages:
209-214
Publication date:
1998-08-14
DOI:
ISSN:
0022-328X
Source identifiers:
51146
Language:
English
Keywords:
Pubs id:
pubs:51146
UUID:
uuid:cf85906c-351d-4713-a695-e6bf34d99014
Local pid:
pubs:51146
Deposit date:
2012-12-19

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