Journal article icon

Journal article

Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes

Abstract:

The synthesis of a range of dinuclear Cu(II) dithiocarbamate (dtc)-based macrocycles and their characterisation are described. By carefully tuning the size of the aromatic spacer, cavities of different dimensions can be designed. The length and flexibility of the chosen spacer group dictates the intermetallic distance and hence the degree of communication between the two metal centres as evidenced by electrochemical and EPR experiments. This is illustrated by crystallographic evidence that sh...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1016/j.ica.2009.09.052

Authors


Journal:
INORGANICA CHIMICA ACTA More from this journal
Volume:
363
Issue:
6
Pages:
1195-1203
Publication date:
2010-04-05
DOI:
ISSN:
0020-1693
Language:
English
Keywords:
Pubs id:
pubs:52649
UUID:
uuid:cf5b9fb0-59e0-4877-b858-b53909a3b9fd
Local pid:
pubs:52649
Source identifiers:
52649
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP