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Fast and selective photoreduction of CO2 to CO Catalyzed by a complex of carbon monoxide dehydrogenase, TiO2, and Ag nanoclusters

Abstract:

Selective, visible-light-driven conversion of CO2 to CO with a turnover frequency of 20 s–1 under visible light irradiation at 25 °C is catalyzed by an aqueous colloidal system comprising a pseudoternary complex formed among carbon monoxide dehydrogenase (CODH), silver nanoclusters stabilized by polymethacrylic acid (AgNCs-PMAA), and TiO2 nanoparticles. The photocatalytic assembly, which is stable over several hours and for at least 250000 turnovers of the enzyme’s active site, was investigat...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acscatal.7b04308

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Johns College
Role:
Author
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Funding agency for:
Zhang, L
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Funding agency for:
Zhang, L
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Funding agency for:
Armstrong, FA
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Catalysis Journal website
Volume:
8
Issue:
4
Pages:
2789−2795
Publication date:
2018-02-27
Acceptance date:
2018-02-15
DOI:
EISSN:
2155-5435
Pubs id:
pubs:830323
URN:
uri:cf3f7f5d-f583-415b-9241-1d5f25625f84
UUID:
uuid:cf3f7f5d-f583-415b-9241-1d5f25625f84
Local pid:
pubs:830323

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