- Abstract:
- Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield. © 2001 Elsevier Science B.V.
- Publication status:
- Published
- Publisher copy:
- 10.1016/S0022-328X(01)00702-1
-
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- Journal:
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume:
- 628
- Issue:
- 1
- Pages:
- 25-29
- Publication date:
- 2001-05-15
- DOI:
- ISSN:
-
0022-328X
- URN:
-
uuid:cf337c44-903b-493c-a1a1-dd9ff1c56aed
- Source identifiers:
-
51075
- Local pid:
- pubs:51075
- Language:
- English
- Keywords:
- Copyright date:
- 2001
Journal article
Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i)
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