Journal article icon

Journal article

Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i)

Abstract:
Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield. © 2001 Elsevier Science B.V.
Publication status:
Published

Actions


Access Document


Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Expand authors...
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
628
Issue:
1
Pages:
25-29
Publication date:
2001-05-15
DOI:
ISSN:
0022-328X
URN:
uuid:cf337c44-903b-493c-a1a1-dd9ff1c56aed
Source identifiers:
51075
Local pid:
pubs:51075

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP