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Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i)

Abstract:
Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield. © 2001 Elsevier Science B.V.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
628
Issue:
1
Pages:
25-29
Publication date:
2001-05-15
DOI:
ISSN:
0022-328X
Source identifiers:
51075
Language:
English
Keywords:
Pubs id:
pubs:51075
UUID:
uuid:cf337c44-903b-493c-a1a1-dd9ff1c56aed
Local pid:
pubs:51075
Deposit date:
2012-12-19

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