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The ruthenocenylmethylium cation: Isolation and structures of eta(5)-cyclopentadienyl-eta(6)-fulvene-ruthenium(II) salts

Abstract:

Salts of the ruthenocenylmethylium cation, 1+, can be synthesized from the reaction of ruthenocenylmethanol with either Brønsted or Lewis acids. The X-ray crystal structures of the tetrakis{3,5-bis(trifluoromethyl)phenyl}borate and trifluoromethanesulfonate salts of 1+ reveal that the methylium carbon is bound to the ruthenium with Ru-C bond lengths in the range 2.251(9)-2.40(1) Å and confirm the description of the cation structure as η5-cyclopentadienyl-η6-fulvene-ruthenium(II). The UV-vis s...

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Publication status:
Published

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Publisher copy:
10.1021/om010667+

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS
Volume:
20
Issue:
25
Pages:
5351-5359
Publication date:
2001-12-10
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
38036
Language:
English
Pubs id:
pubs:38036
UUID:
uuid:cf2d7fa9-47f9-49bb-bbbe-43417da1c889
Local pid:
pubs:38036
Deposit date:
2012-12-19

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