Journal article
The ruthenocenylmethylium cation: Isolation and structures of eta(5)-cyclopentadienyl-eta(6)-fulvene-ruthenium(II) salts
- Abstract:
-
Salts of the ruthenocenylmethylium cation, 1+, can be synthesized from the reaction of ruthenocenylmethanol with either Brønsted or Lewis acids. The X-ray crystal structures of the tetrakis{3,5-bis(trifluoromethyl)phenyl}borate and trifluoromethanesulfonate salts of 1+ reveal that the methylium carbon is bound to the ruthenium with Ru-C bond lengths in the range 2.251(9)-2.40(1) Å and confirm the description of the cation structure as η5-cyclopentadienyl-η6-fulvene-ruthenium(II). The UV-vis s...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/om010667+
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Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 20
- Issue:
- 25
- Pages:
- 5351-5359
- Publication date:
- 2001-12-10
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Source identifiers:
-
38036
Item Description
- Language:
- English
- Pubs id:
-
pubs:38036
- UUID:
-
uuid:cf2d7fa9-47f9-49bb-bbbe-43417da1c889
- Local pid:
- pubs:38036
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2001
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