- Abstract:
-
Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory of this technique for slow charge transfer processes at spherical electrodes is developed. An explicit analytical solution is deduced applicable to electrodes of any size, whatever the reversibility of the system and the length of the two potential pulses. From this solution we examine the influence on the RPV response of the electrode sphericity and the kinetics of the electrode process. It i...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2010.06.019
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 648
- Issue:
- 1
- Pages:
- 67-77
- Publication date:
- 2010-09-15
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:ceca491d-26ce-4a61-80e9-71911fbd601c
- Source identifiers:
-
90851
- Local pid:
- pubs:90851
- Language:
- English
- Keywords:
- Copyright date:
- 2010
Journal article
Analytical solution for Reverse Pulse Voltammetry at spherical electrodes: A remarkably sensitive method for the characterization of electrochemical reversibility and electrode kinetics
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