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Analytical solution for Reverse Pulse Voltammetry at spherical electrodes: A remarkably sensitive method for the characterization of electrochemical reversibility and electrode kinetics

Abstract:

Reverse Pulse Voltammetry (RPV) is a powerful double pulse technique for kinetic studies. The theory of this technique for slow charge transfer processes at spherical electrodes is developed. An explicit analytical solution is deduced applicable to electrodes of any size, whatever the reversibility of the system and the length of the two potential pulses. From this solution we examine the influence on the RPV response of the electrode sphericity and the kinetics of the electrode process. It i...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
648
Issue:
1
Pages:
67-77
Publication date:
2010-09-15
DOI:
ISSN:
1572-6657
URN:
uuid:ceca491d-26ce-4a61-80e9-71911fbd601c
Source identifiers:
90851
Local pid:
pubs:90851

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