Journal article
New coordination modes for modified Schiff base Ti(IV) complexes and their control over lactone ring-opening polymerization activity
- Abstract:
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A series of eight new bis(alkoxy)bis(phenoxy-imine)titanium(IV) catalysts, coordinated by Schiff base ligands derived from o-vanillin (2-hydroxy-3-methoxybenzaldehyde), show good activity and control for the ring-opening polymerization of ε-caprolactone and ω-pentadecalactone. The new complexes are easily prepared in two high-yield steps from commercial reagents. The new ligands can all adopt two different coordination modes, depending on the steric bulk on the imine: a six-membered N–O chela...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Accepted manuscript, pdf, 696.8KB)
-
- Publisher copy:
- 10.1021/acs.inorgchem.8b02271
Authors
Funding
Siam Cement Group (SCG) Chemicals Co., Ltd
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Inorganic Chemistry Journal website
- Volume:
- 57
- Issue:
- 22
- Pages:
- 14240–14248
- Publication date:
- 2018-10-30
- Acceptance date:
- 2018-10-11
- DOI:
- EISSN:
-
1520-510X
- ISSN:
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0020-1669
Item Description
- Pubs id:
-
pubs:926690
- UUID:
-
uuid:ce862ab1-3b90-4494-8d9e-b124c69b334e
- Local pid:
- pubs:926690
- Source identifiers:
-
926690
- Deposit date:
- 2018-10-11
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- Copyright © 2018 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/acs.inorgchem.8b02271
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