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LINEAR-CHAIN ORGANOMETALLIC ELECTRON-TRANSFER COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF 1-1 AND 2-1 DECAMETHYLFERROCENIUM SALTS OF TRIS[BIS(TRIFLUOROMETHYL)ETHYLENE-1,2-DITHIOLATO]MOLYBDATE ANIONS

Abstract:: The synthesis and crystal structures of two organometallic electron-transfer salts, [Fe(C5Me5)2]x{Mo[S2C 2(CF3)2]3} (x = 1, 2), are reported. For x = 1 the structure consists of discrete linear stacks of alternating S = 1/2 [Fe(C5Me5)2].1 cations and S = 1/2 {Mo[S2C2(CF3)2]3} .- anions with the anions adopting a nearly perfect trigonal prismatic geometry. Crystal data: monoclinic, space group C2/m, a = 22.551 (3) AΔ, b = 12.997 (2) AΔ, c = 14.236 (4) AΔ, β = 91.23 (2)°, V = 4171.4 AΔ3, Z = 4,...
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Publication status:: Published

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APA Style

Heuer, W., Mountford, P., Green, M., Bott, S., Ohare, D., & Miller, J. (1990). LINEAR-CHAIN ORGANOMETALLIC ELECTRON-TRANSFER COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF 1-1 AND 2-1 DECAMETHYLFERROCENIUM SALTS OF TRIS[BIS(TRIFLUOROMETHYL)ETHYLENE-1,2-DITHIOLATO]MOLYBDATE ANIONS. CHEMISTRY OF MATERIALS, 2(6), 764–772.

MLA Style

Heuer, W., et al. “LINEAR-CHAIN ORGANOMETALLIC ELECTRON-TRANSFER COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF 1-1 AND 2-1 DECAMETHYLFERROCENIUM SALTS OF TRIS[BIS(TRIFLUOROMETHYL)ETHYLENE-1,2-DITHIOLATO]MOLYBDATE ANIONS.” CHEMISTRY OF MATERIALS, vol. 2, no. 6, 1990, pp. 764–72.

Chicago Style

Heuer, W, P Mountford, M Green, S Bott, D Ohare, and J Miller. 1990. “LINEAR-CHAIN ORGANOMETALLIC ELECTRON-TRANSFER COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF 1-1 AND 2-1 DECAMETHYLFERROCENIUM SALTS OF TRIS[BIS(TRIFLUOROMETHYL)ETHYLENE-1,2-DITHIOLATO]MOLYBDATE ANIONS.” CHEMISTRY OF MATERIALS 2 (6): 764–72.
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Publisher copy:: 10.1021/cm00012a032

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+ Heuer, W More by this author

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+ Mountford, P More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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+ Green, M More by this author

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+ Bott, S More by this author

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+ Ohare, D More by this author

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Bibliographic Details

Journal:: CHEMISTRY OF MATERIALS
Volume:: 2
Issue:: 6
Pages:: 764-772
Publication date:: 1990-01-01
DOI:: 10.1021/cm00012a032
EISSN:: 1520-5002
ISSN:: 0897-4756

Item Description

Language:: English
Pubs id:: pubs:51386
UUID:: uuid:ce192007-c08c-4900-a156-790d3ef3d060
Local pid:: pubs:51386
Source identifiers:: 51386
Deposit date:: 2012-12-19

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Copyright date:: 1990

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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